9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
نویسندگان
چکیده
In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems. These dimers are further linked by C-H⋯π and C-Br⋯π inter-actions. The cations and anions are connected by multidirectional C-H⋯O and C-F⋯π inter-actions. The acridine and benzene ring systems are oriented at 10.8 (1)°. The carboxyl group is twisted at an angle of 85.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or almost parallel [inclined at an angle of 1.4 (1)°] in the crystal structure.
منابع مشابه
9-(4-Methylphenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(22)H(18)NO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-H⋯π and π-π inter-actions, and the cations and anions are connected by C-H⋯O and C-F⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 3.0 (1)°. The carboxyl group is twisted at an angle of 83.1 (1)° relative to the acridine skeleton....
متن کامل9-(Biphenyl-4-yloxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)-3.994 (2) Å]. These dimers are further linked by C-H⋯O and C-H⋯π inter-actions. The cation and the anion are connected by C-H⋯O inter-actions. The mean plane of the acridine ring...
متن کامل9-(4-Chlorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.987 (2) Å], and neighboring cations and anions via C-H⋯O and C-F⋯π inter-actions. The acridine ring system and benzene ring are oriented at a dihedral angle of 1.0 (1)° while the carboxyl group is twisted at an angle of 85.0 ...
متن کامل9-[(2,6-Dimethoxyphenoxy)carbonyl]-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(23)H(20)NO(4) (+)·CF(3)SO(3) (-), the cations are linked through C-H⋯O, C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.641 (2) and 3.885 (2) Å]. The cation and the anion are held together by C-H⋯O and S-O⋯π inter-actions. The acridine ring system and the benzene ring in the cation are oriented at a dihedral angle of 8.7 (1)°. The c...
متن کامل9-(4-Fluorophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(21)H(15)FNO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through C-H⋯O, C-F⋯π and π-π inter-actions. These dimers are further linked by π-π inter-actions. The cations and anions are connected through C-H⋯O, C-F⋯π and S-O⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 74.1 (1)°. The carboxyl...
متن کامل